Staff directory

Neus Domingo Marimón

Senior Researcher
neus.domingo(ELIMINAR)@icn2.cat
Oxide Nanophysics

Publications

2017

  • Lateral Magnetically Modulated Multilayers by Combining Ion Implantation and Lithography

    Menéndez E., Modarresi H., Petermann C., Nogués J., Domingo N., Liu H., Kirby B.J., Mohd A.S., Salhi Z., Babcock E., Mattauch S., Van Haesendonck C., Vantomme A., Temst K. Small; 13 (11, 1603465) 2017. 10.1002/smll.201603465.

    The combination of lithography and ion implantation is demonstrated to be a suitable method to prepare lateral multilayers. A laterally, compositionally, and magnetically modulated microscale pattern consisting of alternating Co (1.6 µm wide) and Co-CoO (2.4 µm wide) lines has been obtained by oxygen ion implantation into a lithographically masked Au-sandwiched Co thin film. Magnetoresistance along the lines (i.e., current and applied magnetic field are parallel to the lines) reveals an effective positive giant magnetoresistance (GMR) behavior at room temperature. Conversely, anisotropic magnetoresistance and GMR contributions are distinguished at low temperature (i.e., 10 K) since the O-implanted areas become exchange coupled. This planar GMR is principally ascribed to the spatial modulation of coercivity in a spring-magnet-type configuration, which results in 180° Néel extrinsic domain walls at the Co/Co-CoO interfaces. The versatility, in terms of pattern size, morphology, and composition adjustment, of this method offers a unique route to fabricate planar systems for, among others, spintronic research and applications. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim


  • Production of biofunctionalized MoS2 flakes with rationally modified lysozyme: A biocompatible 2D hybrid material

    Siepi M., Morales-Narváez E., Domingo N., Monti D.M., Notomista E., Merkoçi A. 2D Materials; 4 (3, 035007) 2017. 10.1088/2053-1583/aa7966.

    Bioapplications of 2D materials embrace demanding features in terms of environmental impact, toxicity and biocompatibility. Here we report on the use of a rationally modified lysozyme to assist the exfoliation of Mos2 bulk crystals suspended in water through ultrasonic exfoliation. The design of the proposed lysozyme derivative provides this exfoliated 2D-materail with both, hydrophobic groups that interact with the surface of Mos2 and hydrophilic groups exposed to the aqueous medium, which hinders its re-Aggregation. This approach, clarified also by molecular docking studies, leads to a stable material (ζ-potential, 27 ?} 1 mV) with a yield of up to 430 μg ml-1. The bio-hybrid material was characterized in terms of number of layers and optical properties according to different slots separated by diverse centrifugal forces. Furthermore the obtained material was proved to be biocompatible using human normal keratinocytes and human cancer epithelial cells, whereas the method was demonstrated to be applicable to produce other 2D materials such as graphene. This approach is appealing for the advantageous production of high quality Mos2 flakes and their application in biomedicine and biosensing. Moreover, this method can be applied to different starting materials, making the denatured lysozyme a promising bio-Tool for surface functionalization of 2D materials. © 2017 IOP Publishing Ltd.


2016

  • Conductance of Threading Dislocations in InGaAs/Si Stacks by Temperature-CAFM Measurements

    Couso C., Iglesias V., Porti M., Claramunt S., Nafría M., Domingo N., Cordes A., Bersuker G. IEEE Electron Device Letters; 37 (5, 7422696): 640 - 643. 2016. 10.1109/LED.2016.2537051. IF: 2.528

    The stacks of III-V materials, grown on the Si substrate, that are considered for the fabrication of highly scaled devices tend to develop structural defects, in particular threading dislocations (TDs), which affect device electrical properties. We demonstrate that the characteristics of the TD sites can be analyzed by using the conductive atomic force microscopy technique with nanoscale spatial resolution within a wide temperature range. In the studied InGaAs/Si stacks, electrical conductance through the TD sites was found to be governed by the Poole-Frenkel emission, while the off-TDs conductivity is dominated by the thermionic emission process. © 1980-2012 IEEE.


  • Ferroelectric Domain Structures in Low-Strain BaTiO3

    Everhardt A.S., Matzen S., Domingo N., Catalan G., Noheda B. Advanced Electronic Materials; 2 (1, 1500214) 2016. 10.1002/aelm.201500214. IF: 0.000

    Epitaxial strain in ferroelectric films offers the possibility to enhance the piezoelectric performance utilizing low crystal symmetries and high density of domain walls. Ferroelectric BaTiO3 has been predicted to order in a variety of phases and domain configurations when grown under low strain on low mismatched substrates, but little experimental evidence of that region of the phase diagram exist. Here, epitaxial BaTiO3 thin films are grown on NdScO3 substrates under ≈0.1% strain. A monoclinic ca1/ca2 phase, with 90° periodic in-plane domain configuration and small additional out-of-plane component of polarization, is stabilized at room temperature and investigated using piezoelectric force microscopy and X-ray diffraction. Above 50 °C, this phase is transformed into an a/c phase with alternating in-plane and out-of-plane polarizations and forming zigzag domain walls between up-polarized and down-polarized superdomains. Both types of domain patterns are highly anisotropic, giving rise to very long domain walls. Above 130 °C, the paraelectric phase is observed. The occurrence of a phase transition close to room temperature, a low symmetry ca1/ca2 phase, and the formation of periodic domains make of this material a promising candidate for high piezoelectric response. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim


  • Freezing the Nonclassical Crystal Growth of a Coordination Polymer Using Controlled Dynamic Gradients

    Rubio-Martinez M., Imaz I., Domingo N., Abrishamkar A., Mayor T.S., Rossi R.M., Carbonell C., deMello A.J., Amabilino D.B., Maspoch D., Puigmartí-Luis J. Advanced Materials; : 8150 - 8155. 2016. 10.1002/adma.201506462. IF: 18.960

    [No abstract available]


  • Identification of HIV-1–Based Virus-like Particles by Multifrequency Atomic Force Microscopy

    González-Domínguez I., Gutiérrez-Granados S., Cervera L., Gòdia F., Domingo N. Biophysical Journal; 111 (6): 1173 - 1179. 2016. 10.1016/j.bpj.2016.07.046. IF: 3.632

    Virus-like particles (VLPs) have become a promising platform for vaccine production. VLPs are formed by structural viral proteins that inherently self-assemble when expressed in a host cell. They represent a highly immunogenic and safe vaccine platform, due to the absence of the viral genome and its high protein density. One of the most important parameters in vaccine production is the quality of the product. A related bottleneck in VLP-based products is the presence of cellular vesicles as a major contaminant in the preparations, which will require the set up of techniques allowing for specific discrimination of VLPs from host vesicular bodies. In this work novel, to our knowledge, multifrequency (MF) atomic force microscopy (AFM) has permitted full structural nanophysical characterization by its access to the virus capsid of the HIV-based VLPs. The assessment of these particles by advanced amplitude modulation-frequency modulation (AM-FM) viscoelastic mapping mode has enhanced the imaging resolution of their nanomechanical properties, opening a new window for the study of the biophysical attributes of VLPs. Finally, the identification and differentiation of HIV-based VLPs from cellular vesicles has been performed under ambient conditions, providing, to our knowledge, novel methodology for the monitoring and quality control of VLPs. © 2016 Biophysical Society


  • Monolithic integration of room-temperature multifunctional BaTiO 3 -CoFe 2 O 4 epitaxial heterostructures on Si(001)

    Scigaj M., Dix N., Gázquez J., Varela M., Fina I., Domingo N., Herranz G., Skumryev V., Fontcuberta J., Sánchez F. Scientific Reports; 6 ( 31870) 2016. 10.1038/srep31870. IF: 5.228

    The multifunctional (ferromagnetic and ferroelectric) response at room temperature that is elusive in single phase multiferroic materials can be achieved in a proper combination of ferroelectric perovskites and ferrimagnetic spinel oxides in horizontal heterostructures. In this work, lead-free CoFe 2 O 4 /BaTiO 3 bilayers are integrated with Si(001) using LaNiO 3 /CeO 2 /YSZ as a tri-layer buffer. They present structural and functional properties close to those achieved on perovskite substrates: the bilayers are fully epitaxial with extremely flat surface, and exhibit robust ferromagnetism and ferroelectricity at room temperature. © The Author(s) 2016.


  • Piezoelectric Templates - New Views on Biomineralization and Biomimetics

    Stitz N., Eiben S., Atanasova P., Domingo N., Leineweber A., Burghard Z., Bill J. Scientific Reports; 6 ( 26518) 2016. 10.1038/srep26518. IF: 5.228

    Biomineralization in general is based on electrostatic interactions and molecular recognition of organic and inorganic phases. These principles of biomineralization have also been utilized and transferred to bio-inspired synthesis of functional materials during the past decades. Proteins involved in both, biomineralization and bio-inspired processes, are often piezoelectric due to their dipolar character hinting to the impact of a template's piezoelectricity on mineralization processes. However, the piezoelectric contribution on the mineralization process and especially the interaction of organic and inorganic phases is hardly considered so far. We herein report the successful use of the intrinsic piezoelectric properties of tobacco mosaic virus (TMV) to synthesize piezoelectric ZnO. Such films show a two-fold increase of the piezoelectric coefficient up to 7.2 pm V-1 compared to films synthesized on non-piezoelectric templates. By utilizing the intrinsic piezoelectricity of a biotemplate, we thus established a novel synthesis pathway towards functional materials, which sheds light on the whole field of biomimetics. The obtained results are of even broader and general interest since they are providing a new, more comprehensive insight into the mechanisms involved into biomineralization in living nature.


  • Spontaneous formation of spiral-like patterns with distinct periodic physical properties by confined electrodeposition of Co-In disks

    Golvano-Escobal I., Gonzalez-Rosillo J.C., Domingo N., Illa X., López-Barberá J.F., Fornell J., Solsona P., Aballe L., Foerster M., Surinãch S., Baró M.D., Puig T., Pané S., Nogués J., Pellicer E., Sort J. Scientific Reports; 6 ( 30398) 2016. 10.1038/srep30398. IF: 5.228

    Spatio-temporal patterns are ubiquitous in different areas of materials science and biological systems. However, typically the motifs in these types of systems present a random distribution with many possible different structures. Herein, we demonstrate that controlled spatio-temporal patterns, with reproducible spiral-like shapes, can be obtained by electrodeposition of Co-In alloys inside a confined circular geometry (i.e., in disks that are commensurate with the typical size of the spatio-temporal features). These patterns are mainly of compositional nature, i.e., with virtually no topographic features. Interestingly, the local changes in composition lead to a periodic modulation of the physical (electric, magnetic and mechanical) properties. Namely, the Co-rich areas show higher saturation magnetization and electrical conductivity and are mechanically harder than the In-rich ones. Thus, this work reveals that confined electrodeposition of this binary system constitutes an effective procedure to attain template-free magnetic, electric and mechanical surface patterning with specific and reproducible shapes.


  • Water Affinity and Surface Charging at the z-Cut and y-Cut LiNbO3 Surfaces: An Ambient Pressure X-ray Photoelectron Spectroscopy Study

    Cordero-Edwards K., Rodríguez L., Calò A., Esplandiu M.J., Pérez-Dieste V., Escudero C., Domingo N., Verdaguer A. Journal of Physical Chemistry C; 120 (42): 24048 - 24055. 2016. 10.1021/acs.jpcc.6b05465. IF: 4.509

    Polarization dependence of water adsorption and desorption on LiNbO3 surfaces was demonstrated using X-ray photoelectron spectroscopy (XPS) carried out in situ under near-ambient conditions. Positive and negative (0001) faces (z-cut) of the same crystal were compared for the same temperature and pressure conditions. Our results indicate a preferential adsorption on the positive face of the crystal with increasing water pressure and also higher desorption temperature of the adsorbed molecular water at the positive face. Adsorption measurements on the (1100) face (y-cut) showed also strong affinity to water, as observed for the z-cut positive surface. We found a direct relation between the capacity of the surface to discharge and/or to screen surface charges and the affinity for water of each face. XPS spectra indicate the presence of OH groups at the surface for all the conditions and surfaces measured. © 2016 American Chemical Society.


2015

  • Enhanced conduction and ferromagnetic order at (100)-type twin walls in L a0.7 S r0.3Mn O3 thin films

    Balcells L., Paradinas M., Baguès N., Domingo N., Moreno R., Galceran R., Walls M., Santiso J., Konstantinovic Z., Pomar A., Casanove M.-J., Ocal C., Martínez B., Sandiumenge F. Physical Review B - Condensed Matter and Materials Physics; 92 (7, 075111) 2015. 10.1103/PhysRevB.92.075111. IF: 3.736

    There is increasing evidence supporting the strong potential of twin walls in ferroic materials as distinct, spatially tunable, functional elements in future electronic devices. Here, we report an increase of about one order of magnitude in conductivity and more robust magnetic interactions at (100)-type twin walls in La0.7Sr0.3MnO3 thin films. The nature and microscopic origin of such distinctive behavior is investigated by combining conductive, magnetic, and force modulation scanning force microscopies with transmission electron microscopy techniques. Our analyses indicate that the observed behavior is due to a severe compressive strained state within an ∼1nm slab of material centered at the twin walls, promoting stronger Mn 3d-O2p orbital overlapping leading to a broader bandwidth and enhanced magnetic interactions. © 2015 American Physical Society.


  • Giant reversible nanoscale piezoresistance at room temperature in Sr2IrO4 thin films

    Domingo N., López-Mir L., Paradinas M., Holy V., Železný J., Yi D., Suresha S.J., Liu J., Rayan Serrao C., Ramesh R., Ocal C., Martí X., Catalan G. Nanoscale; 7 (8): 3453 - 3459. 2015. 10.1039/c4nr06954d. IF: 7.394

    Layered iridates have been the subject of intense scrutiny on account of their unusually strong spin-orbit coupling, which opens up a narrow bandgap in a material that would otherwise be a metal. This insulating state is very sensitive to external perturbations. Here, we show that vertical compression at the nanoscale, delivered using the tip of a standard scanning probe microscope, is capable of inducing a five orders of magnitude change in the room temperature resistivity of Sr2IrO4. The extreme sensitivity of the electronic structure to anisotropic deformations opens up a new angle of interest on this material, with the giant and fully reversible perpendicular piezoresistance rendering iridates as promising materials for room temperature piezotronic devices. This journal is © The Royal Society of Chemistry.


  • Persistence of ferroelectricity above the Curie temperature at the surface of Pb(Z n1/3 N b2/3) O3-12%PbTi O3

    Domingo N., Bagués N., Santiso J., Catalan G. Physical Review B - Condensed Matter and Materials Physics; 91 (9, 094111) 2015. 10.1103/PhysRevB.91.094111. IF: 3.736

    Relaxor-based ferroelectrics have been known for decades to possess a relatively thick surface layer ("skin") that is distinct from its interior. Yet while there is consensus about its existence, there are controversies about its symmetry, phase stability, and origin. In an attempt to clarify these issues, we have examined the surface layer of PZN-12%PT. While the bulk transitions from a ferroelastically twinned tetragonal ferroelectric state with in-plane polarization to a cubic paraphase at Tc=200C, the skin layer shows a robust labyrinthine nanodomain structure with out-of-plane polarization that persists hundreds of degrees above the bulk Curie temperature. Cross-sectional transmission electron microscopy analysis shows that the resilience of the skin's polarization is correlated with a compositional imbalance: lead vacancies at the surface are charge-compensated by niobium enrichment; the excess of Nb5+ - a small ion with d0 orbital occupancy - stabilizes the ferroelectricity of the skin layer. © 2015 American Physical Society.


  • Revealing water films structure from force reconstruction in dynamic AFM

    Calò A., Domingo N., Santos S., Verdaguer A. Journal of Physical Chemistry C; 119 (15): 8258 - 8265. 2015. 10.1021/acs.jpcc.5b02411. IF: 4.772

    The structure of water films in contact with surfaces has direct implications in many important interfacial processes, from biology to climatology, as well as in ice nucleation. Here we report on the detection of individual ice-like water layers adsorbed on surfaces in ambient conditions. Reconstructed force profiles obtained in amplitude modulation atomic force microscopy (AM-AFM) on top of (111) BaF2 surfaces, with a lattice constant close to the distance of facing water molecules in hexagonal ice (Ih), showed characteristic oscillations in the attractive regime with a periodicity of 3.7 Å. This distance matches the thickness of a bilayer of Ih ice and is absent in force profiles on (111) CaF2 surfaces, which show a different lattice parameter. A thickness of 2.6 Å is measured for the first water layer in contact with the surface, corresponding to a high-density liquid film structure predicted from calculations in the literature. Our results indicate that, although epitaxial Ih growth of the first water layer on BaF2 crystals is not observed, the matching of the lattice parameter between Ih and BaF2 does induce a strong ordering of the water films and the formation of ice-like structures, even at room temperature. © 2015 American Chemical Society.


2014

  • Electrocatalytic tuning of biosensing response through electrostatic or hydrophobic enzyme-graphene oxide interactions

    Baptista-Pires, L.; Pérez-López, B.; Mayorga-Martinez, C.C.; Morales-Narváez, E.; Domingo, N.; Esplandiu, M.J.; Alzina, F.; Torres, C.M.S.; Merkoçi, A. Biosensors and Bioelectronics; 61: 655 - 662. 2014. 10.1016/j.bios.2014.05.028. IF: 6.451


  • Spectroscopy methods for molecular nanomagnets

    Baker, M.L.; Blundell, S.J.; Domingo, N.; Hill, S. Structure and Bonding; 164: 231 - 292. 2014. 10.1007/430-2014-155. IF: 1.836


2013

  • Local properties of the surface layer(s) of BiFeO3 single crystals

    Domingo, N.; Narvaez, J.; Alexe, M.; Catalan, G. Journal of Applied Physics; 113 2013. 10.1063/1.4801974. IF: 2.210


  • Surface screening of written ferroelectric domains in ambient conditions

    Segura, J.J.; Domingo, N.; Fraxedas, J.; Verdaguer, A. Journal of Applied Physics; 113 2013. 10.1063/1.4801983. IF: 2.210


2012

  • Advances on structuring, integration and magnetic characterization of molecular nanomagnets on surfaces and devices

    Domingo, N.; Bellido, E.; Ruiz-Molina, D. Chemical Society Reviews; 41: 258 - 302. 2012. 10.1039/c1cs15096k.


  • Controlled positioning of nanoparticles on graphene by noninvasive AFM lithography

    Bellido, E.; Ojea-Jiménez, I.; Ghirri, A.; Alvino, C.; Candini, A.; Puntes, V.; Affronte, M.; Domingo, N.; Ruiz-Molina, D. Langmuir : the ACS journal of surfaces and colloids; 28: 12400 - 12409. 2012. 10.1021/la3023419.


  • Structuration and integration of magnetic nanoparticles on surfaces and devices

    Bellido, E.; Domingo, N.; Ojea-Jiménez, I.; Ruiz-Molina, D. Small; 8: 1465 - 1491. 2012. 10.1002/smll.201101456.


2010

  • Interface exchange coupling in Co nanoparticles dispersed in a Mn matrix

    Binns, C. ; Domingo, N. ; Testa, A.M.; Fiorani, D. ; Trohidou, K.N. ; Vasilakaki, M ; Blackman, J.A.; Asaduzzaman, A.M.; Baker, S.; Roy, M.; Peddis, D. Journal of Physics Condensed Matter; 22: 436005 - 6 paginas. 2010. 10.1088/0953-8984/22/43/436005.


  • Metal-radical chains based on polychlorotriphenylmethyl radicals: Synthesis, structure, and magnetic properties

    Roques, N.; Domingo, N.; Maspoch, D.; Wurst, K.; Rovira, C.; Tejada, J.; Ruiz-Molina, D.; Veciana, J. Inorganic Chemistry; 49: 3482 - 3488. 2010. 10.1021/ic100037z.


2009

  • Particle-size dependence of magnetization relaxation in Mn12 crystals

    Domingo, N.; Luis, F.; Nakano, M.; Muntó, M.; Gómez, J.; Chaboy, J.; Ventosa, N.; Campo, J.; Veciana, J.; Ruiz-Molina, D. Physical Review B - Condensed Matter and Materials Physics; 79 2009. 10.1103/PhysRevB.79.214404.


2007

  • First-row transition-metal complexes based on a carboxylate polychlorotriphenylmethyl radical: Trends in metal-radical exchange interactions

    Maspoch, D.; Domingo, N.; Ruiz-Molina, D.; Wurst, K.; Hernández, J.M.; Lloret, F.; Tejada, J.; Rovira, C.; Veciana, J. Inorganic Chemistry; 46: 1627 - 1633. 2007. 10.1021/ic061815x.


  • Structural and magnetic modulation of a purely organic open framework by selective guest inclusion

    Maspoch, D.; Domingo, N.; Roques, N.; Wurst, K.; Tejada, J.; Rovira, C.; Ruiz-Molina, D.; Veciana, J. Chemistry - A European Journal; 13: 8153 - 8163. 2007. 10.1002/chem.200700353.


2005

  • An unusually stable trinuclear manganese(II) complex bearing bulk carboxylic radical ligands

    Maspoch, D.; Gómez-Segura, J.; Domingo, N.; Ruiz-Molina, D.; Wurst, K.; Rovira, C.; Tejada, J.; Veciana, J. Inorganic Chemistry; 44: 6936 - 6938. 2005. 10.1021/ic050977a.


  • Carboxylic-substituted polychlorotriphenylmethyl radicals, new organic building-blocks to design nanoporous magnetic molecular materials

    Maspoch, D.; Domingo, N.; Ruiz-Molina, D.; Wurst, K.; Tejada, J.; Rovira, C.; Veciana, J. Comptes Rendus Chimie; 8: 1213 - 1225. 2005. 10.1016/j.crci.2005.02.020.


  • Coexistence of ferro- and antiferromagnetic interactions in a metal-organic radical-based (6,3)-helical network with large channels

    Maspoch, D.; Domingo, N.; Ruiz-Molina, D.; Wurst, K.; Hernández, J.-M.; Vaughan, G.; Rovira, C.; Lloret, F.; Tejada, J.; Veciana, J. Chemical Communications; : 5035 - 5037. 2005. 10.1039/b505827a.


  • Hydrogen-bonded self-assemblies in a polychlorotriphenylmethyl radical derivative substituted with six meta-carboxylic acid groups

    Roques, N.; Maspoch, D.; Domingo, N.; Ruiz-Molina, D.; Wurst, K.; Tejada, J.; Rovira, C.; Veciana, J. Chemical Communications; : 4801 - 4803. 2005. 10.1039/b508952b.


2004

  • A Robust Nanocontainer Based on a Pure Organic Free Radical

    Maspoch, D.; Domingo, N.; Ruiz-Molina, D.; Wurst, K.; Tejada, J.; Rovira, C.; Veciana, J. Journal of the American Chemical Society; 126: 730 - 731. 2004. 10.1021/ja038988v.


  • A robust purely organic nanoporous magnet

    Maspoch, D.; Domingo, N.; Ruiz-Molina, D.; Wurst, K.; Vaughan, G.; Tejada, J.; Rovira, C.; Veciana, J. Angewandte Chemie - International Edition; 43: 1828 - 1832. 2004. 10.1002/anie.200353358.


  • Chiral, single-molecule nanomagnets: Synthesis, magnetic characterization and natural and magnetic circular dichroism

    Gerbier, P.; Domingo, N.; Gómez-Segura, J.; Ruiz-Molina, D.; Amabilino, D.B.; Tejada, J.; Williamson, B.E.; Veciana, J. Journal of Materials Chemistry; 14: 2455 - 2460. 2004. 10.1039/b403062a.


  • Magnetism of isolated Mn12 single-molecule magnets detected by magnetic circular dichroism: Observation of spin tunneling with a magneto-optical technique

    Domingo, N.; Williamson, B.E.; Gómez-Segura, J.; Gerbier, Ph.; Ruiz-Molina, D.; Amabilino, D.B.; Veciana, J.; Tejada, J. Physical Review B; 69: 524051 - 524054. 2004. .


  • Open-shell channel-like salts formed by the supramolecular assembly of a tricarboxylated perchlorotriphenylmethyl radical and a [Co(bpy) 3]2+ cation

    Maspoch, D.; Ruiz-Molina, D.; Wurst, K.; Vaughan, G.; Domingo, N.; Tejada, J.; Rovira, C.; Veciana, J. CrystEngComm; 6: 573 - 578. 2004. 10.1039/b410810h.