Staff directory

Publications

2017

  • Symmetry forbidden morphologies and domain boundaries in nanoscale graphene islands

    Parreiras S.O., Gastaldo M., Moreno C., Martins M.D., Garcia-Lekue A., Ceballos G., Paniago R., Mugarza A. 2D Materials; 4 (2, 025104) 2017. 10.1088/2053-1583/aa70fa. IF: 6.937

    The synthesis of graphene nanoislands with tailored quantum properties requires an atomic control of the morphology and crystal structure. As one reduces their size down to the nanometer scale, domain boundary and edge energetics, as well as nucleation and growth mechanisms impose different stability and kinetic landscape from that at the microscale. This offers the possibility to synthesize structures that are exclusive to the nanoscale, but also calls for fundamental growth studies in order to control them. By employing high-resolution scanning tunneling microscopy we elucidate the atomic stacking configurations, domain boundaries, and edge structure of graphene nanoislands grown on Ni(1 1 1) by CVD and post-annealed at different temperatures. We find a non-conventional multistep mechanism that separates the thermal regimes for growth, edge reconstruction, and final stacking configuration, leading to nanoisland morphologies that are incompatible with their stacking symmetry. Whole islands shift their stacking configuration during cooling down, and others present continuous transitions at the edges. A statistical analysis of the domain structures obtained at different annealing temperatures reveals how polycrystalline, ill-defined structures heal into shape-selected islands of a single predominant stacking. The high crystallinity and the control on morphology and edge structure makes these graphene nanoislands ideal for their application in optoelectronics and spintronics. © 2017 IOP Publishing Ltd.


2015

  • Atomic species identification at the (101) anatase surface by simultaneous scanning tunnelling and atomic force microscopy

    Stetsovych O., Todorovi A.M., Shimizu T.K., Moreno C., Ryan J.W., León C.P., Sagisaka K., Palomares E., Matolín V., Fujita D., Perez R., Custance O. Nature Communications; 6 ( 7265) 2015. 10.1038/ncomms8265. IF: 11.470

    Anatase is a pivotal material in devices for energy-harvesting applications and catalysis. Methods for the accurate characterization of this reducible oxide at the atomic scale are critical in the exploration of outstanding properties for technological developments. Here we combine atomic force microscopy (AFM) and scanning tunnelling microscopy (STM), supported by first-principles calculations, for the simultaneous imaging and unambiguous identification of atomic species at the (101) anatase surface. We demonstrate that dynamic AFM-STM operation allows atomic resolution imaging within the materiala € s band gap. Based on key distinguishing features extracted from calculations and experiments, we identify candidates for the most common surface defects. Our results pave the way for the understanding of surface processes, like adsorption of metal dopants and photoactive molecules, that are fundamental for the catalytic and photovoltaic applications of anatase, and demonstrate the potential of dynamic AFM-STM for the characterization of wide band gap materials. © 2015 Macmillan Publishers Limited. All rights reserved.