Staff directory Alex Gutierrez Fernandez

Alex Gutierrez Fernandez

Visiting Degree Student
UAB
alex.gutierrez(ELIMINAR)@icn2.cat
Magnetic Nanostructures

Publications

2019

  • Diverse structural assemblies and influence in morphology of different parameters in a series of 0D and 1D mercury(II) metal–organic coordination complexes by sonochemical process

    Mohammadi M.K., Gutiérrez A., Hayati P., Mohammadi K., Rezaei R. Polyhedron; 160: 20 - 34. 2019. 10.1016/j.poly.2018.12.016. IF: 2.284

    Four new mercury coordination supramolecular complexes (1D and 0D), [Hg(L)(Br)2]n (1), [Hg(L)(Cl)2]n (2), [Hg(L)(SCN)2]n (3) and [Hg2(L)2(I)4] (4) where L = C6H8N2 (3-picolylamine), have been synthesized under different experimental conditions. Micrometric crystals (bulk) or nano-sized materials have been obtained depending on using the branch tube method or sonochemical irradiation. All materials have been characterized by scanning electron microscopy (SEM), powder X-ray diffraction (PXRD) and FT-IR spectroscopy. Single crystal X-ray analyses on complexes 1–4 show that Hg2+ ions are 4, 5, 4 and 4-coordinated, respectively. Topological analysis shows that the complexes 1–4 are 2C1, 2,2,4C1, 2C1 and 1,2,4M16-1 net, respectively. Also, by changing counter ions, various structures were obtained: 1–4 (0D and 1D) which are helical chain, linear chain and rectangular molecule. The role of different parameters like temperature, reaction time, power of ultrasound irradiation and concentration of initial reactants on the growth and morphology of the micro-nano structures are studied. © 2018 Elsevier Ltd


2018

  • Sonochemical synthesis of a novel nanoscale 1D lead(II) [Pb2(L)2(I)4]n coordination Polymer, survey of temperature, reaction time parameters

    Hayati P., Suárez-García S., Gutiérrez A., Molina D.R., Morsali A., Rezvani A.R. Ultrasonics Sonochemistry; 42: 320 - 326. 2018. 10.1016/j.ultsonch.2017.11.033. IF: 6.012

    One new lead(II) coordination supramolecular complex (CSC) (1D), [Pb2(L)2(I)4]n, L = C4H6N2 (1-methyl imidazole), has been synthesized under different experimental conditions. Micrometric crystals (bulk) or nano-sized materials have been obtained depending on using the branch tube method or sonochemical irradiation. All materials have been characterized by scanning electron microscopy (SEM), powder X-ray diffraction (PXRD) and FT-IR spectroscopy. Single crystal X-ray analyses on complex 1 showed that Pb2+ ion is 4-coordinated. Topological analysis shows that the complex 1 is 2,3,5C2 net. Finally, the role of reaction time and temperature on the growth and final morphology of the structures obtained by sonochemical irradiation have been studied. © 2017 Elsevier B.V.


  • Sonochemical synthesis of two novel Pb(II) 2D metal coordination polymer complexes: New precursor for facile fabrication of lead(II) oxide/bromide micro-nanostructures

    Hayati P., Suárez-García S., Gutierrez A., Şahin E., Molina D.R., Morsali A., Rezvani A.R. Ultrasonics Sonochemistry; 42: 310 - 319. 2018. 10.1016/j.ultsonch.2017.11.037. IF: 6.012

    Two new lead(II) coordination polymer complexes (CSCs) (2D), [Pb2(L)2(Br)2]n·H2O (1), [Pb2(HL/)(L/)(H2O)2]n·H2O (2), where L = C6H5NO2 (2-pyridinecarboxylic acid) and L/ = C9H6O6 (1,3,5-tricarboxylic acid), have been synthesized under different experimental conditions. Micrometric crystals (bulk) or microsized materials have been obtained depending on using the branch tube method or sonochemical irradiation. All materials have been characterized by scanning electron microscopy (SEM), powder X-ray diffraction (PXRD) and FT-IR spectroscopy. Single crystal X-ray analyses on complexes 1 and 2 shows that Pb2+ ions are 8-coordinated, 7 and 9-coordinated, respectively. Topological analysis shows that the compound 1 and 2 are 4,6L26 and bnn net, respectively. However, neither the shape nor the morphology is maintained, showing the role of sonochemistry to modulate both morphology and dimensions of the resulting crystalline material, independently of whether we have a 2D coordination polymer (CP). Finally, micro structuration of lead(II) bromide oxide and lead(II) oxide have been prepared by calcination of two different lead (II) CPs at 700 °C that were characterized by SEM and XRD. © 2017 Elsevier B.V.


2017

  • Sonochemical synthesis and characterization of a novel hetro-binuclear metal organic nano polymer based on picolinic acid ligand

    Hayati P., Sori B., Rezvani A.R., Morsali A., Gutierrez A. Journal of Molecular Structure; 1150: 404 - 410. 2017. 10.1016/j.molstruc.2017.09.006. IF: 1.753

    Nanoparticles of one new lead and K coordination polymer (CP), {[Pb6(pyc)6(N3)7K].½H2O}n (1) Hpyc = picolinic acid ligand, has been synthesized by use of a sonochemical process and characterized by scanning electron microscopy (SEM), X-ray powder diffraction (XRPD), Fourier transform infrared spectroscopy (FTIR) spectroscopy and elemental analyses. The single crystal X-ray data of compound 1 imply that the Pb ion is seven coordinated. The thermal stability of compound 1 has been studied by thermogravimetric (TG) and differential scanning calorimetry (DSC). The role of temperature, reaction time and ultrasound irradiation power on the size and morphfology of the nano-structured compound obtained from 1, have been investigated. Results indicate that an increase of temperature and sonication power and a decrease in time reaction led to a decrease of particle size. © 2017 Elsevier B.V.