Staff directory Miguel Ángel Moreno Villaecija

Miguel Ángel Moreno Villaecija

Doctoral Student
FPI-PREDOC SO
miguelangel.moreno(ELIMINAR)@icn2.cat
Nanostructured Functional Materials

Publications

2019

  • Ammonium hexadeca-oxo-heptavanadate microsquares. A new member in the family of the V7O16 mixed-valence nanostructures

    Navas D., Donoso J.P., Magon C., Sotomayor-Torres C.M., Moreno M., Lozano H., Benavente E., González G. New Journal of Chemistry; 43 (45): 17548 - 17556. 2019. 10.1039/c9nj02188d. IF: 3.069

    This paper presents a new mixed valence heptavanadate (NH4)2V7O16, obtained from a two-stage treatment in a single container of ammonium metavanadate with hexadecylamine in an acetic medium. The hydrolysis of the precursor under normal conditions leads to an intermediate, layered hybrid nanocomposite, V2O5/alkylamine, which after an in situ hydrothermal treatment is transformed almost quantitatively into an amine-free microcrystalline phase constituted by perfect square microparticles of (NH4)2V7O16. The analysis of composition, structure and morphology of the product points to a mixed valence vanadium oxide with a high content of V(iv) (approximately 73%). The microsquares have a tetragonal structure similar to that of BaV7O16, as well as to those proposed for the VOx/amine hybrid nanocomposite series: nanotubes, nano urchins and the compound (en)V7O16. The results suggest that all these phases belong to the V7O16 family, but that they differ in the amine content, the degree of reduction and the curvature of the network. The feasibility of obtaining flat nanostructures based on V7O16 without templates, beyond demonstrating the robustness of the structural unit V7O16 in networks with different degrees of reduction and curvatures, clarifies the role of alkylamines in this type of anti-entropic supramolecular process. First, the amine provides a stable platform that allows for an orderly reduction of the network under hydrothermal conditions and, when the medium favours the stability of the V-amine bond, the alkylamine contributes to the driving force that leads to the curving of the V-O network. This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.


  • Versatile Graphene-Based Platform for Robust Nanobiohybrid Interfaces

    Bueno R., Marciello M., Moreno M., Sánchez-Sánchez C., Martinez J.I., Martinez L., Prats-Alfonso E., Guimerà-Brunet A., Garrido J.A., Villa R., Mompean F., García-Hernandez M., Huttel Y., Morales M.D.P., Briones C., López M.F., Ellis G.J., Vázquez L., Martín-Gago J.A. ACS Omega; 4 (2): 3287 - 3297. 2019. 10.1021/acsomega.8b03152. IF: 2.584

    Technologically useful and robust graphene-based interfaces for devices require the introduction of highly selective, stable, and covalently bonded functionalities on the graphene surface, whilst essentially retaining the electronic properties of the pristine layer. This work demonstrates that highly controlled, ultrahigh vacuum covalent chemical functionalization of graphene sheets with a thiol-terminated molecule provides a robust and tunable platform for the development of hybrid nanostructures in different environments. We employ this facile strategy to covalently couple two representative systems of broad interest: metal nanoparticles, via S-metal bonds, and thiol-modified DNA aptamers, via disulfide bridges. Both systems, which have been characterized by a multitechnique approach, remain firmly anchored to the graphene surface even after several washing cycles. Atomic force microscopy images demonstrate that the conjugated aptamer retains the functionality required to recognize a target protein. This methodology opens a new route to the integration of high-quality graphene layers into diverse technological platforms, including plasmonics, optoelectronics, or biosensing. With respect to the latter, the viability of a thiol-functionalized chemical vapor deposition graphene-based solution-gated field-effect transistor array was assessed. © Copyright 2019 American Chemical Society.